The overall ozone (smog) forming potential of biodiesel is less than diesel fuel. The ozone forming potential of the speciated hydrocarbon emissions was nearly 50 percent less than that measured for diesel fuel.
Sulfur emissions are essentially eliminated with pure biodiesel. The exhaust emissions of sulfur oxides and sulfates (major components of acid rain) from biodiesel were essentially eliminated compared to sulfur oxides and sulfates from diesel.
Criteria pollutants are reduced with biodiesel use. Tests show the use of biodiesel in diesel engines results in substantial reductions of unburned hydrocarbons, carbon monoxide, and particulate matter. Emissions of nitrogen oxides stay the same or are slightly increased.
Carbon Monoxide -- The exhaust emissions of carbon monoxide (a poisonous gas) from biodiesel are on average 44 percent lower than carbon monoxide emissions from diesel.
Particulate Matter -- Breathing particulate has been shown to be a human health hazard. The exhaust emissions of particulate matter from biodiesel are about 40 percent lower than overall particulate matter emissions from diesel.
Hydrocarbons -- The exhaust emissions of total hydrocarbons (a contributing factor in the localized formation of smog and ozone) are on average 68 percent lower for biodiesel than diesel fuel.
Nitrogen Oxides -- NOx emissions from biodiesel increase or decrease depending on the engine family and testing procedures. NOx emissions (a contributing factor in the localized formation of smog and ozone) from pure (100%) biodiesel increase on average by 6 percent. However, biodiesel's lack of sulfur allows the use of NOx control technologies that cannot be used with conventional diesel. So, biodiesel NOx emissions can be effectively managed and efficiently eliminated as a concern of the fuel's use.
Biodiesel reduces the health risks associated with petroleum diesel. Biodiesel emissions show decreased levels of PAH and nitrited PAH compounds which have been identified as potential cancer causing compounds. In the recent testing, PAH compounds were reduced by 75 to 85 percent, with the exception of benzo(a)anthracene, which was reduced by roughly 50 percent. Targeted nPAH compounds were also reduced dramatically with biodiesel fuel, with 2-nitrofluorene and 1-nitropyrene reduced by 90 percent, and the rest of the nPAH compounds reduced to only trace levels.